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    碲鎘汞與鈣鈦礦量子點薄膜異質結的界面電子態及其熒光特性

    Study on Interface Electronic States and Fluorescence Properties on Heterostructures of HgCdTe and Perovskite Quantum Dot Films

    • 摘要: 半導體異質結是有源光電子器件最重要的材料組成部分之一。構築了窄帶隙半導體碲鎘汞(Hg0.7Cd0.3Te)和寬帶隙CsPbBr3半導體量子點薄膜的異質結,通過研究發現量子點與碲鎘汞薄膜形成了Type-I異質結,CsPbBr3鈣鈦礦量子點薄膜中的部分電子和空穴在輻射復合前轉移至Hg0.7Cd0.3Te的價帶與導帶上,導致CsPbBr3鈣鈦礦量子點薄膜的熒光強度下降💁🏻‍♂️;此外💱👨🏽,鈣鈦礦電子空穴輻射復合發光的光子能量大於Hg0.7Cd0.3Te的帶隙,部分熒光被Hg0.7Cd0.3Te吸收。最終CsPbBr3鈣鈦礦量子點薄膜異質結的熒光強度下降至單獨CsPbBr3量子點薄膜強度的0.2倍,表明Type-I異質結中Hg0.7Cd0.3Te薄膜因界面的載流子傳輸導致其對CsPbBr3量子點薄膜熒光具有重要的調製作用。

       

      Abstract: Semiconductor heterostructure is one of the most important components of active optoelectronic devices. In this paper, the heterostructures of narrow-band gap Hg0.7Cd0.3Te semiconductor and wide-band gap CsPbBr3 semiconductor quantum dot films were constructed. Through the study, it was found that Type-I heterostructures were formed by the quantum dots and Hg0.7Cd0.3Te film. Some electrons and holes in CsPbBr3 perovskite quantum dot film were transferred to the valence band and conduction band of Hg0.7Cd0.3Te before radiation recombination, resulting in the decrease of fluorescence intensity of CsPbBr3 perovskite quantum dot film. In addition, the photon radiation energy of perovskite was greater than the band gap of Hg0.7Cd0.3Te, and part of the fluorescence was absorbed by Hg0.7Cd0.3Te. Finally, the fluorescence intensity of CsPbBr3 perovskite quantum dots film heterostructure decreased to 0.2 times that of CsPbBr3 quantum dots film alone, indicating that Hg0.7Cd0.3Te film in Type-I heterostructures had an important modulation effect on fluorescence of CsPbBr3 quantum dots film due to carrier transport at the interface.

       

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